The Lutron Hub will only work with Blinds that say they are compatible with Lutron Hub. Bali Z-wave blinds are not compatible with the Lutron Hub. You will need a z-wave compatible hub to work with your blinds.
If you are looking to centralize controlling both your light and your blinds as you have purchased them, do that you can control them both form the same app I think you have two options:
You can buy a Wink Hub and use it to control both your Lutron Lights and your Bali Blinds (Wink Hub supports Lutron's propriatary Caseta system, Z-wave, and Zigbee devices). In this case you would not use the Lutron Hub at all, you would just use Wink Hub and the Wink App.
You can buy a Vera to control the Bali Blinds and you can install a App on your Vera that can talk to your Lutron Hub. With this system you could control your lights from the Lutron App or the Vera App, and your Blinds from the Vera App.
I don't know of many other systems that are natively compatible with Lutron Caseta system other than Wink. HomeSeer and SmartThings might be able to the integration the same way that the Vera does which is you control the Blinds through HomeSeer or SmartThings, and you install a plug-in that then talks to the Lutron hub to bring them together into one system. Wink, SmartThings, or Vera are probably your cheapest/simplest options for controlling your blinds, but I would do a little research and make sure the Bali Z-wave blinds are compatible with the system before buying.